The place or thing opposite or facing across from a given spot (across the street; across from).
駅の向かいに大きなスーパーがある。
There is a large supermarket across from the station.
向かいのアパートの窓から花が見える。
You can see flowers from the window of the apartment across the street.
向いの席の人と話が弾んだ。
I had a lively conversation with the person sitting opposite me.